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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">tumnig</journal-id><journal-title-group><journal-title xml:lang="ru">Известия высших учебных заведений. Нефть и газ</journal-title><trans-title-group xml:lang="en"><trans-title>Oil and Gas Studies</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">0445-0108</issn><issn pub-type="epub">3033-8174</issn><publisher><publisher-name>Industrial University of Tyumen</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.31660/0445-0108-2023-5-55-66</article-id><article-id custom-type="elpub" pub-id-type="custom">tumnig-1150</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>МАТЕРИАЛЫ И КОНСТРУКЦИИ В НЕФТЕГАЗОВОЙ ОТРАСЛИ</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>MATERIALS AND STRUCTURES IN THE OIL AND GAS INDUSTRY</subject></subj-group></article-categories><title-group><article-title>Применение ионной и электронной модификации нитридных покрытий для защиты от коррозии при наводораживании</article-title><trans-title-group xml:lang="en"><trans-title>Application of ionic and electronic modification of nitride coatings for protection against corrosion during hydrogen feature</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Кадыржанов</surname><given-names>К. К.</given-names></name><name name-style="western" xml:lang="en"><surname>Kadyrzhanov</surname><given-names>K. K.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Кадыржанов Кайрат Камалович, доктор физико-математических наук, профессор,</p><p>Астана.</p></bio><bio xml:lang="en"><p>Kairat K. Kadyrzhanov, Doctor of Physics and Mathematics, Professor,</p><p>Astana.</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Козловский</surname><given-names>А. Л.</given-names></name><name name-style="western" xml:lang="en"><surname>Kozlovskiy</surname><given-names>A. L.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Козловский Артем Леонидович, PhD, преподаватель-исследователь,</p><p>г. Астана;г. Атырау.</p></bio><bio xml:lang="en"><p>Artem L. Kozlovskiy, PhD, Teacher-Researcher,</p><p>Astana;Atyrau.</p></bio><email xlink:type="simple">Kozlovskiy.a@inp.kz</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Шлимас</surname><given-names>Д. И.</given-names></name><name name-style="western" xml:lang="en"><surname>Shlimas</surname><given-names>D. I.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Шлимас Дмитрий Игорьевич, PhD, преподаватель-исследователь,</p><p>г. Астана.</p></bio><bio xml:lang="en"><p>Dmitriy I. Shlimas, PhD, Teacher-Researcher,</p><p>Astana.</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Молдабаева</surname><given-names>Г. Ж.</given-names></name><name name-style="western" xml:lang="en"><surname>Moldabaeva</surname><given-names>G. Zh.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Молдабаева Гульназ Жаксылыковна, доктор технических наук, профессор кафедры нефтяной инженерии,</p><p>г. Алматы.</p></bio><bio xml:lang="en"><p>Gulnaz Zh. Moldabayeva, Doctor of Engineering, Professor at the Department of Petroleum Engineering,</p><p>Almaty.</p></bio><xref ref-type="aff" rid="aff-3"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Евразийский национальный университет им. Л. Н. Гумилева</institution><country>Казахстан</country></aff><aff xml:lang="en"><institution>L.N. Gumilyov Eurasian National University</institution><country>Kazakhstan</country></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="ru"><institution>Евразийский национальный университет&#13;
им. Л. Н. Гумилева; Атырауский университет им. Х. Досмухамедова</institution><country>Казахстан</country></aff><aff xml:lang="en"><institution>L.N. Gumilyov Eurasian National University; Atyrau University named after Kh. Dosmukhamedov</institution><country>Kazakhstan</country></aff></aff-alternatives><aff-alternatives id="aff-3"><aff xml:lang="ru"><institution>Казахский национальный исследовательский технический университет имени К. И. Сатпаева</institution><country>Казахстан</country></aff><aff xml:lang="en"><institution>Satbayev University</institution><country>Kazakhstan</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2023</year></pub-date><pub-date pub-type="epub"><day>17</day><month>11</month><year>2023</year></pub-date><volume>0</volume><issue>5</issue><fpage>55</fpage><lpage>66</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Кадыржанов К.К., Козловский А.Л., Шлимас Д.И., Молдабаева Г.Ж., 2023</copyright-statement><copyright-year>2023</copyright-year><copyright-holder xml:lang="ru">Кадыржанов К.К., Козловский А.Л., Шлимас Д.И., Молдабаева Г.Ж.</copyright-holder><copyright-holder xml:lang="en">Kadyrzhanov K.K., Kozlovskiy A.L., Shlimas D.I., Moldabaeva G.Z.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://tumnig.tyuiu.ru/jour/article/view/1150">https://tumnig.tyuiu.ru/jour/article/view/1150</self-uri><abstract><p>Одним из способов повышения устойчивости стальных конструкций и нефтепроводов к процессам наводораживания при эксплуатации является нанесение на них тонких слоев в виде нитридных или оксидных покрытий, которые обладают более высокими показателями устойчивости к коррозионным процессам. В работе представлены результаты оценки применения ионной и электронной модификации нитридных покрытий (TiN), нанесенных на нержавеющую сталь, с целью повышения их устойчивости к процессам наводораживания и деструкции при накоплении водорода в приповерхностном слое, вызывающем его охрупчивание и коррозию. В качестве ионов для модификации покрытий были выбраны ионы O2+ и N2+ с энергией 20 кэВ/заряд, флюенсы облучения составили 1013–1015 ион/см2 . Для проведения модификации с применением электронов были использованы электроны с энергией 500 кэВ и дозами облучения 100–500 кГр. В результате проведенных экспериментов было установлено, что ионная модификация приводит к формированию в структуре дополнительных дислокационных дефектов, накопление которых приводит к увеличению прочности и устойчивости к растрескиванию. В случае электронного облучения основной эффект модификации заключается в тепловом воздействии, приводящем к повышению стабильности кристаллической структуры, а также ее уплотнению. Анализ эффектов наводораживания и коррозии образцов показал, что ионная модификация с флюенсом 5 × 1013 ион/см2 приводит к увеличению стабильности структуры покрытий, а также увеличению потенциалов коррозии.</p></abstract><trans-abstract xml:lang="en"><p>Applying nitride or oxide coatings in the form of thin layers is a method that can enhance steel structures and resilience of oil pipelines against flooding and corrosion. Such coatings have excellent corrosion-resistant properties. The article presents the results of an assessment of the use of both ionic and electronic modifications of nitride coatings (TiN) on stainless steel to enhance its resilience against hydrogenation and degradation processes occurring during the hydrogen accumulation in the surface layer. These processes lead to embrittlement and corrosion of steel. O2+ and N2+ ions with an energy of 20 keV/charge were chosen as ions for modifying the coatings; the irradiation fluences were in the range of 1013-1015 ion/cm2 . Electrons with an energy of 500 keV and radiation doses from 100 to 500 kGy were utilised to carry out the electron modification process. The experimental results indicate that modifying the ionic content contributes to the creation of more dislocation defects in the structure. This accumulation of defects results in improved strength and resistance to cracking. Through electron irradiation, the thermal effect primarily modifies the crystal structure, enhancing both its stability and densification. An analysis of the effect of hydrogenation and corrosion has demonstrated that ionic modification using a fluence of 5 × 1013 ion/cm2 enhances the stability of the coating structure and elevates corrosion potentials.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>наводораживание</kwd><kwd>коррозия</kwd><kwd>деградация</kwd><kwd>нитридные покрытия</kwd><kwd>защитные материалы</kwd><kwd>ионная модификация</kwd></kwd-group><kwd-group xml:lang="en"><kwd>hydrogenation</kwd><kwd>corrosion</kwd><kwd>degradation</kwd><kwd>nitride coatings</kwd><kwd>protective materials</kwd><kwd>ionic modification</kwd></kwd-group><funding-group><funding-statement xml:lang="ru">Данная работа выполнена в рамках программно-целевого финансирования (программа No. BR18574135) при поддержке Комитета науки Министерства науки и высшего образования Республики Казахстан.</funding-statement><funding-statement xml:lang="en">This study was funded under the programme-targeted financing (Programme No. BR18574135) with support from the Committee of Science of the Ministry of Science and Higher Education of the Republic of Kazakhstan.</funding-statement></funding-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Ionomer Optimization for Water Uptake and Swelling in Anion Exchange Membrane Electrolyzer : Oxygen Evolution Electrode / G. Huang, M. Mandal, N. U. Hassan [et al.]. – Text : electronic // Journal of The Electrochemical Society. – 2020. – Vol. 167, Issue 16. – URL: https://doi.org/10.1149/1945-7111/abcde3.</mixed-citation><mixed-citation xml:lang="en">Huang, G., Mandal, M., Hassan, N. U., Groenhout, K., Dobbs, A., Mustain, W. E., &amp; Kohl, P. A. (2020). Ionomer Optimization for Water Uptake and Swelling in Anion Exchange Membrane Electrolyzer: Oxygen Evolution Electrode. Journal of the Electrochemical Society, 167(16). (In English). Available at: https://doi.org/10.1149/1945-7111/abcde3</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Synergistic effects of helium and hydrogen on self-ion-induced swelling of austenitic 18Cr10NiТi stainless steel / O. V. Borodin, V. V. Bryk, A. S. Kalchenko [et al.]. – DOI 10.1016/j.jnucmat.2013.05.022. – Direct text // Journal of Nuclear Materials. – 2013. – Vol. 442, Issue 1–3. – P. S817–S820.</mixed-citation><mixed-citation xml:lang="en">Borodin, O. V., Bryk, V. V., Kalchenko, A. S., Melnichenko, V. V., Voyevodin, V. N., &amp; Garner, F. A. (2013). Synergistic effects of helium and hydrogen on self-ion-induced swelling of austenitic 18Cr10NiТi stainless steel. Journal of Nuclear Materials, 442(1-3), pp. S817-S820. (In English). DOI: 10.1016/j.jnucmat.2013.05.022</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Swelling measurement during sorption and decompression in a NBR exposed to high-pressure hydrogen / S. Castagnet, H. Ono, G. Benoit [et al.]. – DOI 10.1016/J.IJHYDENE.2017.06.138. – Direct text // International Journal of Hydrogen Energy. – 2017. – Vol. 42, Issue 30. – P. 19359–19366.</mixed-citation><mixed-citation xml:lang="en">Castagnet, S., Ono, H., Benoit, G., Fujiwara, H., &amp; Nishimura, S. (2017). Swelling measurement during sorption and decompression in a NBR exposed to highpressure hydrogen. International Journal of Hydrogen Energy, 42(30), pp. 19359-19366. (In English). DOI: 10.1016/J.IJHYDENE.2017.06.138</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Mechanical characterization of reactively magnetron-sputtered TiN films / F. Vaz, P. Machado, L. Rebouta [et al.]. – Direct text // Surface and Coatings Technology. – 2003. – Vol. 174. – P. 375–382.</mixed-citation><mixed-citation xml:lang="en">Vaz, F., Machado, P., Rebouta, L., Cerqueira, P., Goudeau, P., Riviere, J. P., &amp; De Rijk, J. (2003). Mechanical characterization of reactively magnetron-sputtered TiN films. Surface and Coatings Technology, 174, pp. 375-382. (In English).</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Investigation of fracture properties of magnetron-sputtered TiN films by means of a FIB-based cantilever bending technique / S. Massl, W. Thomma, J. Keckes, R. Pippan. – DOI 10.1016/j.actamat.2008.12.018. – Direct text // Acta materialia. – 2009. – Vol. 57, Issue. 6. – P. 1768–1776.</mixed-citation><mixed-citation xml:lang="en">Massl, S., Thomma, W., Keckes, J., &amp; Pippan, R. (2009). Investigation of fracture properties of magnetron-sputtered TiN films by means of a FIB-based cantilever bending technique. Acta materialia, 57(6), pp. 1768-1776. (In English). DOI: 10.1016/j.actamat.2008.12.018</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Influence of particle and energy flux on stress and texture development in magnetron sputtered TiN films / G. Abadias, W. P. Leroy, S. Mahieu, D. Depla. – Text : electronic // Journal of Physics D : Applied Physics. – 2012. – Vol. 46, Issue 5. – URL: https://doi.org/10.1088/0022-3727/46/5/055301.</mixed-citation><mixed-citation xml:lang="en">Abadias, G., Leroy, W. P., Mahieu, S., &amp; Depla, D. (2012). Influence of particle and energy flux on stress and texture development in magnetron sputtered TiN films. Journal of Physics D: Applied Physics, 46(5). (In English). Available at: https://doi.org/10.1088/0022-3727/46/5/055301</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Influence of Friction Stir Processing on the Friction, Wear and Corrosion Mechanisms of Solid-State Additively Manufactured 316L Duplex Stainless Steel / A. Ralls, M. Daroonparvar, A. K. Kasar [et al.]. – Text : electronic // Tribology International. – 2023. – Vol. 178. – URL: https://doi.org/10.1016/j.triboint.2022.108033.</mixed-citation><mixed-citation xml:lang="en">Ralls, A., Daroonparvar, M., Kasar, A. K., Misra, M., &amp; Menezes, P. L. (2022). Influence of Friction Stir Processing on the Friction, Wear and Corrosion Mechanisms of Solid-State Additively Manufactured 316L Duplex Stainless Steel. Tribology International, 178. (In English). Available at: https://doi.org/10.1016/j.triboint.2022.108033</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Ralls, A. M. Friction Stir Processing on the Tribological, Corrosion, and Erosion Properties of Steel : A Review / A. M. Ralls, A. K. Kasar, P. L. Menezes. – DOI 10.3390/jmmp5030097. – Direct text // Journal of Manufacturing and Materials Processing. – 2021. – Vol. 5, Issue 3. – P. 97–103.</mixed-citation><mixed-citation xml:lang="en">Ralls, A. M., Kasar, A. K., &amp; Menezes, P. L. (2021). Friction Stir Processing on the Tribological, Corrosion, and Erosion Properties of Steel: A Review. Journal of Manufacturing and Materials Processing, 5(3), pp. 97-103. (In English). DOI: 10.3390/jmmp5030097</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">The role of electronic energy loss in ion beam modification of materials / W. J. Weber, D. M. Duffy, L. Thomé, Y. Zhang. – Text : electronic // Current Opinion in Solid State and Materials Science. – 2015. – Vol. 19, Issue 1. – URL: https://doi.org/10.1016/j.cossms.2014.09.003.</mixed-citation><mixed-citation xml:lang="en">Weber, W. J., Duffy, D. M., Thomé, L., &amp; Zhang, Y. (2015). The role of electronic energy loss in ion beam modification of materials. Current Opinion in Solid State and Materials Science, 19(1). (In English). Available at: https://doi.org/10.1016/j.cossms.2014.09.003</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Steel thermal sprayed coatings : superficial hardening by Nitrogen ion implantation / M. Belotserkovsky, A. Yelistratov, A. Byeli, V. Kukareko. – Direct text // Welding journal. – 2009. – Vol. 88, Issue 12. – P. 243–248.</mixed-citation><mixed-citation xml:lang="en">Belotserkovsky, M., Yelistratov, A., Byeli, A., &amp; Kukareko, V. (2009). Steel thermal sprayed coatings: superficial hardening by Nitrogen ion implantation. Welding journal, 88(12), pp. 243-248. (In English).</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
