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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">tumnig</journal-id><journal-title-group><journal-title xml:lang="ru">Известия высших учебных заведений. Нефть и газ</journal-title><trans-title-group xml:lang="en"><trans-title>Oil and Gas Studies</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">0445-0108</issn><issn pub-type="epub">3033-8174</issn><publisher><publisher-name>Industrial University of Tyumen</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.31660/0445-0108-2017-5-113-117</article-id><article-id custom-type="elpub" pub-id-type="custom">tumnig-192</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>ХИМИЯ И ХИМИЧЕСКИЕ ТЕХНОЛОГИИ</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>CHEMISTRY AND CHEMICAL TECHNOLOGIES</subject></subj-group></article-categories><title-group><article-title>СОВЕРШЕНСТВОВАНИЕ ПРОЦЕССА ПИРОЛИЗА</article-title><trans-title-group xml:lang="en"><trans-title>PERFECTION OF THE PYROLYSIS PROCESS</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Магарил</surname><given-names>Е. Р.</given-names></name><name name-style="western" xml:lang="en"><surname>Magaril</surname><given-names>E. R.</given-names></name></name-alternatives><email xlink:type="simple">magaril67@mail.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Магарил</surname><given-names>Р. З.</given-names></name><name name-style="western" xml:lang="en"><surname>Magaril</surname><given-names>R. Z.</given-names></name></name-alternatives><email xlink:type="simple">png@tsogu.ru</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Трушкова</surname><given-names>Л. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Trushkova</surname><given-names>L. V.</given-names></name></name-alternatives><email xlink:type="simple">png@tsogu.ru</email><xref ref-type="aff" rid="aff-2"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Уральский федеральный университет им. первого Президента России Б. Н. Ельцина</institution><country>Россия</country></aff><aff xml:lang="en"><institution>Ural Federal University named after the first President of Russia B. N. Yeltsin</institution><country>Russian Federation</country></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="ru"><institution>Тюменский индустриальный университет</institution><country>Россия</country></aff><aff xml:lang="en"><institution>Industrial University of Tyumen</institution><country>Russian Federation</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2017</year></pub-date><pub-date pub-type="epub"><day>30</day><month>10</month><year>2017</year></pub-date><volume>0</volume><issue>5</issue><fpage>113</fpage><lpage>117</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Магарил Е.Р., Магарил Р.З., Трушкова Л.В., 2017</copyright-statement><copyright-year>2017</copyright-year><copyright-holder xml:lang="ru">Магарил Е.Р., Магарил Р.З., Трушкова Л.В.</copyright-holder><copyright-holder xml:lang="en">Magaril E.R., Magaril R.Z., Trushkova L.V.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://tumnig.tyuiu.ru/jour/article/view/192">https://tumnig.tyuiu.ru/jour/article/view/192</self-uri><abstract><p>Получены данные по относительной реакционной способности различных типов связей при взаимодействии с атомами водорода, метильными радикалами, а также по эффективным относительным реакционным способностям при использовании инертного разбавителя, позволяющие углубить знания о пиролизе сырья данного состава. Разработан метод повышения селективности процесса по целевым продуктам (низшим олефинам), снижения выхода жидких продуктов конденсации и удельных энергозатрат, основанный на влиянии водорода на термические реакции алканов и алкенов.</p></abstract><trans-abstract xml:lang="en"><p>There were obtained the values of the relative reactivity of different types of bonds in interaction with hydrogen atoms, methyl radicals, as well as values of the effective relative reactivity when using an inert diluent, enabling to improve knowledge about the pyrolysis of raw materials of a given composition. A method was developed for increasing the selectivity of the pyrolysis for the desired products of the process (lower olefins), reducing the yield of liquid products of condensation and specific energy consumption, based on the influence of hydrogen on the thermal reactions of alkanes and alkenes.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>эффективность пиролиза</kwd><kwd>относительная реакционная способность связей</kwd><kwd>водород</kwd></kwd-group><kwd-group xml:lang="en"><kwd>the effectiveness of pyrolysis</kwd><kwd>relative reactivity of chemical bond</kwd><kwd>hydrogen</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Global Ethylene Market Outlook: Low Cost Feedstocks Fuel The Next Wave Of Investments In North America and China. 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