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Oil emulsion characteristics as significance in efficiency forecast of oil-displacing formulations based on surfactants

https://doi.org/10.31660/0445-0108-2021-3-91-107

Abstract

Enhanced oil recovery in mature fields can be implemented using chemical flooding with the addition of surfactants using surfactant-polymer (SP) or alkaline-surfactant-polymer (ASP) flooding. Chemical flooding design is implemented taking into account reservoir conditions and composition of reservoir fluids. The surfactant in the oil-displacing formulation allows changing the rock wettability, reducing the interfacial tension, increasing the capillary number, and forming an oil emulsion, which provides a significant increase in the efficiency of oil displacement. The article is devoted with a comprehensive study of the formed emulsion phase as a stage of laboratory selection of surfactant for SP or ASP composition. In this work, the influence of aqueous phase salinity level and the surfactant concentration in the displacing solution on the characteristics of the resulting emulsion was studied. It was shown that, according to the characteristics of the emulsion, it is possible to determine the area of optimal salinity and the range of surfactant concentrations that provide increased oil displacement. The data received show the possibility of predicting the area of effectiveness of ASP and SP formulations based on the characteristics of the resulting emulsion.

About the Authors

E. A. Turnaeva
University of Tyumen
Russian Federation

Elena A. Turnaeva, Candidate of Chemistry, Head of the Chromatography and Spectroscopy Sector, Research Resource Center "Natural Resource Management and Physico-Chemical Research"

Tyumen



E. A. Sidorovskaya
University of Tyumen
Russian Federation

Elizaveta A. Sidorovskaya, Engineer, Research Resource Center "Natural Resource Management and Physico-Chemical Research"

Tyumen



D. S. Adakhovskij
University of Tyumen
Russian Federation

Denis S. Adakhovskij, Postgraduate at the Department of Organic and Ecological Chemistry

Tyumen



E. V. Kikireva
University of Tyumen
Russian Federation

Ekaterina V. Kikireva, Engineer, Research Resource Center "Natural Resource Management and Physico-Chemical Research"

Tyumen



N. Yu. Tret'yakov
University of Tyumen
Russian Federation

Nikolai Yu. Tret'yakov, Candidate of Chemistry, Director of Research Resource Center "Natural Resource Management and Physico-Chemical Research", Professor at the Department of Organic and Ecological Chemistry

Tyumen



I. N. Koltsov
Gazpromneft — Technological Partnerships LLC
Russian Federation

Igor N. Koltsov, Expert of EOR Technology Office

St. Petersburg



S. S. Volkova
University of Tyumen
Russian Federation

Svetlana S. Volkova, Candidate of Chemistry, Deputy Director of  Research Resource Center "Natural Resource Management and Physico-Chemical Research, Professor at the Department of Organic and Ecological Chemistry

Tyumen



A. A. Groman
Gazpromneft — Technological Partnerships LLC
Russian Federation

Andrey A. Groman, Head of EOR Technology Office

St. Petersburg



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Review

For citations:


Turnaeva E.A., Sidorovskaya E.A., Adakhovskij D.S., Kikireva E.V., Tret'yakov N.Yu., Koltsov I.N., Volkova S.S., Groman A.A. Oil emulsion characteristics as significance in efficiency forecast of oil-displacing formulations based on surfactants. Oil and Gas Studies. 2021;(3):91-107. (In Russ.) https://doi.org/10.31660/0445-0108-2021-3-91-107

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ISSN 0445-0108 (Print)