PERFECTION OF THE PYROLYSIS PROCESS
https://doi.org/10.31660/0445-0108-2017-5-113-117
Abstract
There were obtained the values of the relative reactivity of different types of bonds in interaction with hydrogen atoms, methyl radicals, as well as values of the effective relative reactivity when using an inert diluent, enabling to improve knowledge about the pyrolysis of raw materials of a given composition. A method was developed for increasing the selectivity of the pyrolysis for the desired products of the process (lower olefins), reducing the yield of liquid products of condensation and specific energy consumption, based on the influence of hydrogen on the thermal reactions of alkanes and alkenes.
About the Authors
E. R. Magaril
Ural Federal University named after the first President of Russia B. N. Yeltsin
Russian Federation
Russian Federation
R. Z. Magaril
Industrial University of Tyumen
Russian Federation
Russian Federation
L. V. Trushkova
Industrial University of Tyumen
Russian Federation
Russian Federation
References
1. Global Ethylene Market Outlook: Low Cost Feedstocks Fuel The Next Wave Of Investments In North America and China. Inaugural Ethylene Forum Online. - Аvailable at: http: www.media.corporateir.net/media_files/IROL/11 /110877/05_Global_Ethylene_Market_Outlook_Eramo.pdf
2. Catalytic processes for light olefin production. (Chapter 5) / X. Q. Wang [and etc.]. - Practical Advances in Petroleum Processing, eds. C. S. Hsu & P. R. Robinson. - New York: Springer Science-Business Media, Inc., 2006. - Vol. 1. - P. 149-168
3. Sadrameli S. M. Thermal/catalytic cracking of hydrocarbons for the production of olefins: A state-of-the-art review I: Thermal cracking review // Fuel. - 2015. - Vol. 140. - P. 102-115
4. Воеводский В. В. Вопросы химической кинетики, катализа и реакционной способности. - М: Изд-во АН СССР, 1955
5. Magaril R. S. Some Problems of the Cracking Mechanism of the Hydrocarbons // Symposium on Refining Petroleum for Chemicals. - 1969. - Vol. 14, № 4. - P. D68-D75
6. Magaril R. S. Some Problems of the Cracking Mechanism of the Hydrocarbons // Refining Petroleum for Chemicals (Chapter 6). - 1970. - Vol. 97. - Р. 110-122
7. Magaril E., Magaril R. Increasing the Selectivity of the Hydrocarbon Feedstock Pyrolysis // WIT Transactions on Ecology and the Environment. - 2014. - Vol. 186. - P. 529-534
8. Demidenko M., Magaril R., Magaril E. Aqueous Vapour Substitution for Hydrogen in the Process of Pyrolysis // WIT Transactions on Ecology and the Environment. - 2014. - Vol. 190 (2). - P. 855-860
9. Демиденко М. Н., Магарил Р. З., Магарил Е. Р. Замена водяного пара на водород в процессе пиролиза // Известия высших учебных заведений. Нефть и газ. - 2014. - № 6. - С. 95-99
Review
For citations:
Magaril E.R., Magaril R.Z., Trushkova L.V. PERFECTION OF THE PYROLYSIS PROCESS. Oil and Gas Studies. 2017;(5):113-117. (In Russ.) https://doi.org/10.31660/0445-0108-2017-5-113-117
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